1. Sign into your Chrome and click the gear icon in the right corner of the screen.
2. Select Settings from the drop down menu.
3. Choose Open a Specific Page or Set of Pages under On Startup and click Set Pages.
4. Enter the URLs for the websites that you want to open when you start Chrome in the dialogue box and click OK.
5. Close and restart Chromeand the URLs your entered should open automatically.
Good luck !